The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

https://www.uv-vis-spectral-atlas-mainz.org, https://uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Hydroxy-,methoxyalkylperoxy / CH2(OH)CH2O2 / Lightfoot(1992)_298K_205-300nm(rec)

DATAFILE: CH2(OH)CH2O2_Lightfoot(1992)_298K_205-300nm(rec).txt
NAME: 2-hydroxyethylperoxy radical
FORMULA: CH2(OH)CH2O2
AUTHOR(YEAR): Lightfoot(1992)
T: 298K
λ: 205-300nm(rec)
BIBLIOGRAPHY: P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry", Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I
COMMENTS: Recommendation based on a smooth fit to the data of

T.P. Murrells, M.E. Jenkin, S.H. Shalliker, and G.D. Hayman, "Laser flash photolysis study of the UV spectrum and kinetics of reactions of HOCH2CH2O2 radicals," J. Chem. Soc. Faraday Trans. 87, 2351-2360 (1991), and

M.E. Jenkin and R.A. Cox, "Kinetics of reactions of CH3O2 and HOCH2CH2O2 radicals produced by the photolysis of iodomethane and 2-iodoethanol," J. Phys. Chem. 95, 3229-3237 (1991), (excluding the points at 270, 280, and 290 nm)

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